Fabrication of cellulose-based polymer electrolyte membrane with green solvent DMSO via N-TIPS technique
نویسندگان
چکیده
Abstract Solid polymer electrolyte membrane for Li-ion battery was fabricated via N-TIPS technique. To substitute commercially available polyolefin-based separator with more sustainable source, cellulose-based employed as matrix. Green solvent dimethylsulfoxide (DMSO) used to replace conventional solvents. Impedance measurement using electrochemical impedance spectroscopy performed determine ionic conductivity of the solid membrane. Room temperature in CR2032 cell 1.1×10 −4 mS/cm, indicating good performance and feasibility application. This result is hundred times higher compared similar route N-methyl pyrrolidone (NMP) (1.38×10 −6 S/cm). Further dielectric properties variation an enclosed chamber showed that obeys Arrhenius behaviour.
منابع مشابه
fabrication of cellulose –silk composite in liquid phase with green solvent
in this research, cellulose-silk composites production in liquid phase was studied. in this respect,bmimcl ionic liquid was synthesized in the laboratory and was used for dissolution purpose. afterdissolution of the biopolymers and mixing them in the liquid phase, obtained suspension was spread ina petri dish. then, the composite gel was washed with running methanol to remove the il, cellulosea...
متن کاملCentral composite experimental design applied to fabrication of LLDPE microporous membrane via thermally induced phase separation (TIPS) method
متن کامل
Fabrication of Nanocomposite Membrane via Combined Electrospinning and Casting Technique for Direct Methanol Fuel Cell
Emergence of nanotechnology has resulted in the introduction of the electrospinning process in fabricating and characterising the polymer electrolyte membrane from the sulfonated poly (ether ether ketone) (SPEEK) nanocomposite membrane comprised of electrospun Cloisite15A® (e-spun CL...
متن کاملFabrication of stable photovoltachromic cells using a solvent-free hybrid polymer electrolyte.
In this work, photovoltachromic cells (PVCCs) are fabricated using a solvent-free polyethylene glycol (PEG)-titanium hybrid polymer electrolyte. With appropriate addition of 1,2-dimethyl-3-propylimidazolium iodide in the electrolyte, the range of tunable colored-state transmittance of the PVCC is enlarged due to an improved fill factor. A transmittance modulation larger than 40% can be maintain...
متن کاملModification of Cellulose with Succinic Anhydride in TBAA/DMSO Mixed Solvent under Catalyst-Free Conditions
Homogeneous modification of cellulose with succinic anhydride was performed using tetrabutylammonium acetate (TBAA)/dimethyl sulfoxide (DMSO) mixed solvent. The molar ratio of succinic anhydride (SA) to free hydroxyl groups in the anhydroglucose units (AGU), TBAA dosage, reaction temperature, and reaction time were investigated. The highest degree of substitution (DS) value of 1.191 was obtaine...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: IOP conference series
سال: 2023
ISSN: ['1757-899X', '1757-8981']
DOI: https://doi.org/10.1088/1755-1315/1239/1/012003